Research Progress on Growth Mechanisms of Helical Carbon Nanofibers
DOI:
https://doi.org/10.51173/jt.v7i3.2725Keywords:
Helical Carbon Nanofibers (HCNFs), Fabrication Methods, Growth MechanismsAbstract
Helical carbon nanofibers (HCNFs), a novel class of nanocarbon materials with a unique three-dimensional helical morphology, inherit many of the intrinsic properties of conventional carbon nanofibers while exhibiting additional characteristics such as superelasticity, unique electromagnetic response behavior, and a highly textured surface topology. These properties make HCNFs highly valuable for applications in electromagnetic shielding, nanosprings, and sensing technologies. Among the various fabrication techniques, chemical vapor deposition remains the most widely used and effective method for producing HCNFs, with structural regulation achieved by controlling parameters such as catalyst type and reaction temperature. Alternative methods such as flame synthesis, electrospinning, and templating have also demonstrated potential in growing HCNFs. Regarding growth mechanisms, the asymmetric carbon deposition and diffusion on catalyst surfaces are considered the primary drivers of the periodic curling behavior observed in HCNFs. Several models, including the three-dimensional growth mechanism, the vapor-liquid-solid-solid mechanism, and the coordination polymerization mechanism, have been proposed to elucidate the formation of helical structures. This review provides a comprehensive overview of recent advancements in HCNF growth mechanisms, emphasizing the roles of precursor materials, catalyst properties, and reaction conditions in achieving precise and controllable synthesis.
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References
W. R. Davis, R. J. Slawson, and G. R. J. N. Rigby, “An Unusual Form of Carbon,” Nature, vol. 171, no. 4356, pp. 756-756, 1953,http://dx.doi.org/10.1038/171756a0.
J. F. Wen, Y. Zhang, N. J. Tang, X. G. Wan, Z. H. Xiong, W. Zhong, Z. L. Wang, X. L. Wu, and Y. W. Du, “Synthesis, Photoluminescence, and Magnetic Properties of Nitrogen-Doping Helical Carbon Nanotubes,” Journal of Physical Chemistry C, vol. 115, no. 25, pp. 12329-12334, Jun 30, 2011,http://dx.doi.org/10.1021/jp202723f.
M. Z. M. Zhang, Y. N. Y. Nakayama, and L. P. L. J. J. J. o. A. P. Pan, “Synthesis of carbon tubule nanocoils in high yield using iron-coated indium tin oxide as catalyst,” Japanese Journal of Applied Physics, vol. 39, no. 12A, pp. L1242, 2000,http://dx.doi.org/1347-4065/39/12A/L1242.
S. Motojima, and Q. J. J. o. A. P. Chen, “Three-dimensional growth mechanism of cosmo-mimetic carbon microcoils obtained by chemical vapor deposition,” Journal of Applied Physics, vol. 85, no. 7, pp. 3919-3921, 1999,http://dx.doi.org/10.1063/1.369765.
X. Chen, and S. J. C. Motojima, “The growth patterns and morphologies of carbon micro-coils produced by chemical vapor deposition,” Carbon, vol. 37, no. 11, pp. 1817-1823, 1999,http://dx.doi.org/10.1016/S0008-6223(99)00054-8.
Y. Shang, Y. Li, X. He, L. Zhang, Z. Li, P. Li, E. Shi, S. Wu, and A. Cao, “Elastic carbon nanotube straight yarns embedded with helical loops,” Nanoscale, vol. 5, no. 6, pp. 2403-10, Mar 21, 2013,http://dx.doi.org/10.1039/c3nr33633f.
J. C. Ruiz-Cornejo, D. Sebastián, and M. J. Lázaro, “Synthesis and applications of carbon nanofibers: a review,” Reviews in Chemical Engineering, vol. 36, no. 4, pp. 493-511, May 2020,http://dx.doi.org/10.1515/revce-2018-0021.
D. Yadav, F. Amini, and A. Ehrmann, “Recent advances in carbon nanofibers and their applications - A review,” European Polymer Journal, vol. 138, no. 138-, pp. 138, Sep 5, 2020,http://dx.doi.org/10.1016/j.eurpolymj.2020.109963.
Shuiliang, Chen, Haoqing, Hou, Ping, Hu, Joachim, H., Wendorff, A. J. M. Materials, and Engineering, “Polymeric Nanosprings by Bicomponent Electrospinning,” Macromolecular Materials and Engineering, 2009,http://dx.doi.org/10.1002/mame.200800342.
Z. Ren, and P. X. Gao, “A review of helical nanostructures: growth theories, synthesis strategies and properties,” Nanoscale, vol. 6, no. 16, pp. 9366-400, Aug 21, 2014,http://dx.doi.org/10.1039/c4nr00330f.
P. E. S. Silva, F. Vistulo de Abreu, and M. H. Godinho, “Shaping helical electrospun filaments: a review,” Soft Matter, vol. 13, no. 38, pp. 6678-6688, Oct 4, 2017,http://dx.doi.org/10.1039/c7sm01280b.
D. C. Wang, Y. Lei, W. Jiao, Y. F. Liu, and X. Jian, “A review of helical carbon materials structure, synthesis and applications,” Rare Metals, vol. 40, no. 1, pp. 17, 2021,http://dx.doi.org/10.1007/s12598-020-01622-y.
R. Cui, D. Xu, X. Xie, Y. Yi, and G. J. F. C. Zhang, “Phosphorus-doped helical carbon nanofibers as enhanced sensing platform for electrochemical detection of carbendazim,” Food Chemistry, vol. 221, pp. 457-463, 2017,http://dx.doi.org/10.1016/j.foodchem.2016.10.094.
Xinglong, Zheng, Yongzhong, Jin, Jian, Chen, Binghong, Li, Qingshan, and F. J. J. o. M. Science, “Mechanical properties and microstructure characterization of natural rubber reinforced by helical carbon nanofibers,” Journal of Materials Science, vol. 54, no. 19, pp. 12962–12971, 2019,http://dx.doi.org/10.1007/s10853-019-03771-7.
X. Guo, X. Li, L. Xia, L. Ma, W. Lü, and K. J. A. A. N. M. Li, “Controllable Preparation of Helical Carbon Nanofibers for Electromagnetic Wave Absorption,” ACS Applied Nano Materials, vol. 7, no. 17, pp. 10, 2024,http://dx.doi.org/10.1021/acsanm.4c03454.
D. Jiang, Y. Jin, W. Zhang, X. Li, G. Chen, and Y. J. J. o. E. C. Liu, “Helical carbon nanofibers-supported MnSiO3 for high-performance lithium-ion battery anode materials,” Electrochimica Acta, pp. 977, 2025,http://dx.doi.org/10.1016/j.electacta.2025.146844.
X. X. Zhou, Y. Wang, C. C. Gong, B. Liu, and G. Wei, “Production, structural design, functional control, and broad applications of carbon nanofiber-based nanomaterials: A comprehensive review,” Chemical Engineering Journal, vol. 402, pp. 126189, Dec 15, 2020,http://dx.doi.org/10.1016/j.cej.2020.126189.
Y. Qin, Z. Zhang, and Z. J. C. Cui, “Helical carbon nanofibers with a symmetric growth mode,” Carbon, vol. 42, no. 10, pp. 1917-1922, 2004,http://dx.doi.org/10.1016/j.carbon.2004.03.020.
N. Tang, W. Zhong, A. Gedanken, and Y. Du, “High magnetization helical carbon nanofibers produced by nanoparticle catalysis,” J Phys Chem B, vol. 110, no. 24, pp. 11772-4, Jun 22, 2006,http://dx.doi.org/10.1021/jp060004b.
L. Yu, Y. Qin, and Z. J. M. L. Cui, “Synthesis of coiled carbon nanofibers by Cu–Ni alloy nanoparticles catalyzed decomposition of acetylene at the low temperature of 241° C,” Materials Letters, vol. 59, no. 4, pp. 459-462, 2005,http://dx.doi.org/10.1016/j.matlet.2004.10.021.
J. L. Fajardo-Díaz, S. M. Durón-Torres, F. López-Urías, and E. Muñoz-Sandoval, “Synthesis, characterization and cyclic voltammetry studies of helical carbon nanostructures produced by thermal decomposition of ethanol on Cu-foils,” Carbon, vol. 155, pp. 469-482, Dec, 2019,http://dx.doi.org/10.1016/j.carbon.2019.09.015.
R. Cui, Z. Han, and J. J. Zhu, “Helical carbon nanotubes: intrinsic peroxidase catalytic activity and its application for biocatalysis and biosensing,” Chemistry, vol. 17, no. 34, pp. 9377-84, Aug 16, 2011,http://dx.doi.org/10.1002/chem.201100478.
I. J. D. Priscillal, S. F. Wang, and S. Kameoka, “Investigation on the influence of reaction temperature on the structural and magnetic properties of morphologically diverse carbon nanotubes synthesized using LaNi5Pt0.5 alloy catalyst,” Journal of Alloys and Compounds, vol. 958, pp. 170355, Oct 5, 2023,http://dx.doi.org/10.1016/j.jallcom.2023.170355.
H. Radnia, A. Rashidi, and A. R. S. Nazar, “Synthesis of Helical and Straight Carbon Nanofibers on Water Soluble Sodium Chloride Supported Catalyst,” Journal of Inorganic and Organometallic Polymers and Materials, vol. 30, no. 5, pp. 1600-1608, May, 2020,http://dx.doi.org/10.1007/s10904-019-01381-z.
Y. Z. Jin, J. Chen, Q. S. Fu, B. H. Li, H. Z. Zhang, and Y. Gong, “Low-temperature synthesis and characterization of helical carbon fibers by one-step chemical vapour deposition,” Applied Surface Science, vol. 324, pp. 438-442, Jan 1, 2015,http://dx.doi.org/10.1016/j.apsusc.2014.10.107.
X. Jian, M. Jiang, Z. W. Zhou, Q. Zeng, J. Lu, D. C. Wang, J. T. Zhu, J. H. Gou, Y. Wang, D. Hui, and M. L. Yang, “Gas-Induced Formation of Cu Nanoparticle as Catalyst for High-Purity Straight and Helical Carbon Nanofibers,” Acs Nano, vol. 6, no. 10, pp. 8611-8619, Oct, 2012,http://dx.doi.org/10.1021/nn301880w.
Y. Suda, K. Maruyama, T. Iida, H. Takikawa, H. Ue, K. Shimizu, and Y. Umeda, “High-Yield Synthesis of Helical Carbon Nanofibers Using Iron Oxide Fine Powder as a Catalyst,” Crystals, vol. 5, no. 1, pp. 47-60, Mar, 2015,http://dx.doi.org/10.3390/cryst5010047.
Y. Li, S. Guo, L. Zhao, S. Chen, Y. Li, X. Yang, P. Wang, W. Feng, Z. Mou, and H. J. C. Jiang, “Controlled preparation of lightweight, resilient helical carbon fibers for high-performance microwave absorption and oil-water separation,” Carbon, vol. 233, pp. 119923, 2025,http://dx.doi.org/10.1016/j.carbon.2024.119923.
X. Xiong, P. Zhao, R. Ren, X. Cui, and S. Ji, “Flame-Synthesis of Carbon Nanotube Forests on Metal Mesh Structure: Dependence, Morphology, and Application,” Nanomaterials (Basel), vol. 9, no. 9, pp. 1188, Aug 22, 2019,http://dx.doi.org/10.3390/nano9091188.
W. Zhang, Q. S. Fu, X. D. Chen, Z. X. Yu, Y. Z. Jin, N. Q. Liu, Y. P. Sheng, L. L. Xiao, and J. Chen, “Facile yet versatile assembling of helical carbon nanofibers via metal-organic frameworks burned in ethanol flame and their electrochemical properties as electrode of supercapacitor,” Journal of Power Sources, vol. 521, pp. 230908, Feb 15, 2022,http://dx.doi.org/10.1016/j.jpowsour.2021.230908.
L. Thirugnanam, M. Palanisamy, S. Kaveri, S. Ramaprabhu, V. G. Pol, and M. Dutta, “TiO nanoparticle embedded nitrogen doped electrospun helical carbon nanofiber-carbon nanotube hybrid anode for lithium-ion batteries,” International Journal of Hydrogen Energy, vol. 46, no. 2, pp. 2464-2478, Jan 6, 2021,http://dx.doi.org/10.1016/j.ijhydene.2020.10.149.
X. Zha, Y. Chen, H. Fan, Y. Yang, Y. Xiong, G. Xu, K. Yan, Y. Wang, Y. Xie, and D. J. A. C. I. E. Wang, “Handedness Inversion of Chiral 3‐Aminophenol Formaldehyde Resin Nanotubes Mediated by Metal Coordination,” Angewandte Chemie, vol. 60, no. 14, pp. 7759-7769, 2021,http://dx.doi.org/10.1002/ange.202013790.
Z. L. Xiao, Y. M. Guo, B. Z. Li, and Y. Li, “Preparation and Characterization of Single-handed Helical Carbonaceous Nanofibers using 1,4-Phenylene Bridged Polybissilsesquioxanes,” Journal of Wuhan University of Technology-Materials Science Edition, vol. 31, no. 5, pp. 1149-1154, Oct, 2016,http://dx.doi.org/10.1007/s11595-016-1504-7.
E. J. Cho, L. T. P. Trinh, Y. Song, Y. G. Lee, and H. J. Bae, “Bioconversion of biomass waste into high value chemicals,” Bioresource Technology, vol. 298, pp. 122386, Feb, 2020,http://dx.doi.org/10.1016/j.biortech.2019.122386.
W. Wang, A. Saeed, J. He, Z. Wang, D. Zhan, Z. Li, C. Wang, Y. Sun, F. Tao, and W. Xu, “Bio-inspired porous helical carbon fibers with ultrahigh specific surface area for super-efficient removal of sulfamethoxazole from water,” J Colloid Interface Sci, vol. 578, pp. 304-314, Oct 15, 2020,http://dx.doi.org/10.1016/j.jcis.2020.05.117.
J. Gavillet, A. Loiseau, C. Journet, F. Willaime, F. Ducastelle, and J. C. Charlier, “Root-growth mechanism for single-wall carbon nanotubes,” Phys Rev Lett, vol. 87, no. 27 Pt 1, pp. 275504, Dec 31, 2001,http://dx.doi.org/10.1103/PhysRevLett.87.275504.
M. Kawaguchi, K. Nozaki, S. Motojima, and H. J. J. o. C. G. Iwanaga, “A growth mechanism of regularly coiled carbon fibers through acetylene pyrolysis,” Journal of Crystal Growth, vol. 118, no. 3-4, pp. 309-313, 1992,http://dx.doi.org/10.1016/0022-0248(92)90077-v.
R. S. Wagner, and W. C. J. A. p. l. Ellis, “Vapor‐liquid‐solid mechanism of single crystal growth,” Applied Physics Letters, vol. 4, no. 5, pp. 89-90, 1964,http://dx.doi.org/10.1063/1.1753975.
X. Chen, T. Saito, M. Kusunoki, and S. J. J. o. m. r. Motojima, “Three-dimensional vapor growth mechanism of carbon microcoils,” Journal of Materials Research, vol. 14, no. 11, pp. 4329-4336, 1999,http://dx.doi.org/10.1557/JMR.1999.0586.
X. Chen, S. Yang, and S. J. M. l. Motojima, “Morphology and growth models of circular and flat carbon coils obtained by the catalytic pyrolysis of acetylene,” Materials Letters, vol. 57, no. 1, pp. 48-54, 2002,http://dx.doi.org/10.1016/s0167-577x(02)00697-3.
S. Motojima, X. Chen, S. Yang, M. J. D. Hasegawa, and R. Materials, “Properties and potential applications of carbon microcoils/nanocoils,” Diamond and Related Materials, vol. 13, no. 11-12, pp. 1989-1992, 2004,http://dx.doi.org/10.1016/j.diamond.2004.06.020.
W. J. Li, H. T. Xu, Y. C. Guo, and L. J. J. A. P.-C. S. Chen, “Vapor-Liquid-Solid-Solid Growth Mechanism of Carbon Micro-coils,” Acta Physico-Chimica Sinica, 2006,http://dx.doi.org/10.3866/PKU.WHXB20060625.
A. Shaikjee, and N. J. Coville, “The role of the hydrocarbon source on the growth of carbon materials,” Carbon, vol. 50, no. 10, pp. 3376-3398, Aug, 2012,http://dx.doi.org/10.1016/j.carbon.2012.03.024.
F. Nitze, E. Abou-Hamad, and T. Wågberg, “Carbon nanotubes and helical carbon nanofibers grown by chemical vapour deposition on C fullerene supported Pd nanoparticles,” Carbon, vol. 49, no. 4, pp. 1101-1107, Apr, 2011,http://dx.doi.org/10.1016/j.carbon.2010.11.015.
X. A. Jian, M. Jiang, Z. W. Zhou, M. L. Yang, J. Lu, S. C. Hu, Y. Wang, and D. Hui, “Preparation of high purity helical carbon nanofibers by the catalytic decomposition of acetylene and their growth mechanism,” Carbon, vol. 48, no. 15, pp. 4535-4541, Dec, 2010,http://dx.doi.org/10.1016/j.carbon.2010.08.035.
F. B. Meng, Y. Wang, Q. Wang, X. L. Xu, M. Jiang, X. S. Zhou, P. He, and Z. W. Zhou, “High-purity helical carbon nanotubes by trace-water-assisted chemical vapor deposition: Large-scale synthesis and growth mechanism,” Nano Research, vol. 11, no. 6, pp. 3327-3339, Jun, 2018,http://dx.doi.org/10.1007/s12274-017-1897-4.
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Copyright (c) 2025 Xialong Cai, Rongling Zhang, Wei Feng, Hanjun Wei, Ying Li, Mazin S. Ibrahim, Shrouq Z. Almaaitah

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