Recent Progress in MXene-Based Intelligent Electromagnetic Interference Shielding Materials

Wei Feng; Xialong Cai; Rongling Zhang; Hanjun Wei; Ying Li; Elenwa Elizabeth Pinima; Ali Rahman

doi:10.51173/jt.v7i4.2729

Authors

Wei Feng School of Mechanical Engineering, Chengdu University, 2025 Chengluo Avenue, Chengdu 610106, China
Xialong Cai School of Mechanical Engineering, Chengdu University, 2025 Chengluo Avenue, Chengdu 610106, China
Rongling Zhang School of Mechanical Engineering, Chengdu University, 2025 Chengluo Avenue, Chengdu 610106, China
Hanjun Wei Institute for Advanced Study, Chengdu University, 2025 Chengluo Avenue, Chengdu 610106, China
Ying Li School of Mechanical Engineering, Chengdu University, 2025 Chengluo Avenue, Chengdu 610106, China
Elenwa Elizabeth Pinima Kenule Beeson Saro-Wiwa Polytechnic, Bori, Rivers State, Nigeria
Ali Rahman University of Leeds, Leeds, United Kingdom

DOI:

https://doi.org/10.51173/jt.v7i4.2729

Keywords:

Stimuli-Responsive MXene Composites, Electromagnetic Interference Shielding, Smart Materials

Abstract

As the intelligent era advances at a rapid pace, the increasingly intricate electromagnetic environment is generating an urgent demand for high-performance, intelligent electromagnetic interference (EMI) shielding materials. Endowed with intrinsic high conductivity, superior hydrophilicity, abundant surface chemistry, and tailorable microstructure, MXenes serve as an ideal platform for constructing next-generation intelligent EMI shielding materials. This review elaborates on the design strategies and response mechanisms of MXene-based intelligent EMI shielding materials with different response types. It specifically clarifies the structure-activity relationship between the evolution of material microstructure and the dynamic modulation of electromagnetic parameters. It reveals the advantages and limitations of different systems through comparative analysis.

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Author Biographies

Wei Feng, School of Mechanical Engineering, Chengdu University, 2025 Chengluo Avenue, Chengdu 610106, China

Pursuing a postgraduate degree at the School of Mechanical Engineering, Chengdu University.

Xialong Cai, School of Mechanical Engineering, Chengdu University, 2025 Chengluo Avenue, Chengdu 610106, China

Rongling Zhang, School of Mechanical Engineering, Chengdu University, 2025 Chengluo Avenue, Chengdu 610106, China

Pursuing a postgraduate degree at the School of Mechanical Engineering, Chengdu University.

Hanjun Wei, Institute for Advanced Study, Chengdu University, 2025 Chengluo Avenue, Chengdu 610106, China

Ph.D., is a Distinguished Associate Research Fellow, Associate Professor, and Master's Supervisor at the Advanced Research Institute of Chengdu University.

Ying Li, School of Mechanical Engineering, Chengdu University, 2025 Chengluo Avenue, Chengdu 610106, China

Elenwa Elizabeth Pinima, Kenule Beeson Saro-Wiwa Polytechnic, Bori, Rivers State, Nigeria

Ali Rahman, University of Leeds, Leeds, United Kingdom

References

D. Dai, Z. Wang, and J. E. J. O. L. Bowers, “Ultrashort broadband polarization -beam splitter based on an asymmetrical directional coupler,” Advanced Materials, vol. 36, no. 13, pp. 2590-2592, 2011, http://dx.doi.org/10.1002/adma.202202982.

C. Maosheng, W. Xixi, C. Wenqiang, F. Xiaoyong, W. Bo, and Y. J. S. Jie, “Thermally Driven Transport and Relaxation Switching Self-Powered Electromagnetic Energy Conversion,” Small, pp. 1800987-, 2018, http://dx.doi.org/10.1002/smll.201800987.

O. Pitkänen, J. Tolvanen, I. Szenti, A. k. Kukovecz, J. Hannu, H. Jantunen, K. J. A. A. M. Kordas, and Interfaces, “Lightweight hierarchical carbon nanocomposites with highly efficient and tunable electromagnetic interference shielding properties,” ACS Applied Materials & Interfaces, vol. 11, no. 21, pp. 19331-19338, 2019, http://dx.doi.org/10.1021/acsami.9b21048.

D. X. Yan, H. Pang, B. Li, R. Vajtai, L. Xu, P. G. Ren, J. H. Wang, and Z. M. J. A. F. M. Li, “Structured reduced graphene oxide/polymer composites for ultra‐efficient electromagnetic interference shielding,” Advanced Functional Materials, vol. 25, no. 4, pp. 559-566, 2015, http://dx.doi.org/10.1002/adfm.201403809.

X. Zhou, P. Min, Y. Liu, M. Jin, Z.-Z. Yu, and H.-B. J. S. Zhang, “Insulating electromagnetic-shielding silicone compound enables direct potting electronics,” Science, vol. 385, no. 6714, pp. 1205-1210, 2024, http://dx.doi.org/10.1126/science.adp6581.

S. M. Zachariah, Y. Grohens, N. Kalarikkal, and S. J. P. C. Thomas, “Hybrid materials for electromagnetic shielding: A review,” Polymer Composites, vol. 43, no. 5, pp. 2507-2544, 2022, http://dx.doi.org/10.1002/pc.26595.

Y. Yang, C.-L. Luo, X.-D. Chen, M. J. C. S. Wang, and Technology, “Sustainable electromagnetic shielding graphene/nanocellulose thin films with excellent joule heating and mechanical properties via in-situ mechanical exfoliation and crosslinking with cations,” Composites Science and Technology, vol. 233, pp. 109913, 2023, http://dx.doi.org/10.1016/j.compscitech.2023.109913.

Y. Wang, Y.-N. Gao, T.-N. Yue, X.-D. Chen, and M. J. A. S. S. Wang, “Achieving high-performance and tunable microwave shielding in multi-walled carbon nanotubes/polydimethylsiloxane composites containing liquid metals,” Composites Part B: Engineering, vol. 563, pp. 150255, 2021, http://dx.doi.org/10.1016/j.compositesb.2022.110402.

J.-R. Tao, C.-L. Luo, M.-L. Huang, Y.-X. Weng, M. J. C. P. A. A. S. Wang, and Manufacturing, “Construction of unique conductive networks in carbon nanotubes/polymer composites via poly (ε-caprolactone) inducing partial aggregation of carbon nanotubes for microwave shielding enhancement,” Composites Part A: Applied Science and Manufacturing, vol. 164, pp. 107304, 2023, http://dx.doi.org/10.1016/j.compositesa.2022.107304.

Q. M. He, J. R. Tao, and D. J. C. e. j. Yang, “Surface wrinkles enhancing electromagnetic interference shielding of copper coated poly dime thy lsiloxane: A simulation and experimental study,” Chemical Engineering Journal, 2023, http://dx.doi.org/10.1016/j.cej.2022.140162.

S. Verma, M. Dhangar, S. Paul, K. Chaturvedi, M. A. Khan, and A. K. J. E. M. L. Srivastava, “Recent advances for fabricating smart electromagnetic interference shielding textile: a comprehensive review,” Electronic Materials Letters, vol. 18, no. 4, pp. 331-344, 2022, http://dx.doi.org/10.1007/s13391-022-00344-w.

Y. Xia, W. Gao, and C. J. A. F. M. Gao, “A review on graphene‐based electromagnetic functional materials: electromagnetic wave shielding and absorption,” Advanced Functional Materials, vol. 32, no. 42, pp. 2204591, 2022, http://dx.doi.org/10.1002/adfm.202204591.

M. Naguib, O. Mashtalir, J. Carle, V. Presser, J. Lu, L. Hultman, Y. Gogotsi, and M. W. J. A. n. Barsoum, “Two-dimensional transition metal carbides,” ACS Nano, vol. 6, no. 2, pp. 1322-1331, 2012, http://dx.doi.org/10.1021/nn204153h.

B. Anasori, M. R. Lukatskaya, and Y. Gogotsi, "2D metal carbides and nitrides (MXenes) for energy storage," Nature Reviews Materials, pp. 677-722: Jenny Stanford Publishing, 2023.

M. Naguib, V. N. Mochalin, M. W. Barsoum, and Y. J. A. m. Gogotsi, “25th anniversary article: MXenes: a new family of two‐dimensional materials,” Advanced Materials, vol. 26, no. 7, pp. 992-1005, 2014, http://dx.doi.org/10.1002/adma.201304138.

C. Caloz, and T. Itoh, Electromagnetic metamaterials: transmission line theory and microwave applications, : John Wiley & Sons, 2005.

Z. Fan, D. Wang, Y. Yuan, Y. Wang, and Z. J. C. E. J. Xie, “A lightweight and conductive MXene/graphene hybrid foam for superior electromagnetic interference shielding,” Chemical Engineering Journal, vol. 381, pp. 122696, 2019, http://dx.doi.org/10.1016/j.cej.2019.122696.

X. Jia, B. Shen, L. Zhang, and W. J. C. P. B. E. Zheng, “Waterproof MXene-decorated wood-pulp fabrics for high-efficiency electromagnetic interference shielding and Joule heating,” Composites Part B: Engineering, vol. 198, pp. 108250, 2020, http://dx.doi.org/10.1016/j.compositesb.2020.108250.

X. Li, X. Yin, M. Han, C. Song, X. Sun, H. Xu, L. Cheng, and L. J. J. m. c. c. Zhang, “A controllable heterogeneous structure and electromagnetic wave absorption properties of Ti2CTx MXene,” Journal of Materials Chemistry C, pp. 10.1039.C7TC01991B, 2017, http://dx.doi.org/doi.org/10.1039/c7tc01991b.

J. Luo, S. Gao, H. Luo, L. Wang, X. Huang, Z. Guo, X. Lai, L. Lin, R. K. Li, and J. J. C. E. J. Gao, “Superhydrophobic and breathable smart MXene-based textile for multifunctional wearable sensing electronics,” Chemical Engineering Journal, vol. 406, pp. 126898, 2021, http://dx.doi.org/10.1016/j.cej.2020.126898.

H. Shi, M. Yue, C. J. Zhang, Y. Dong, P. Lu, S. Zheng, H. Huang, J. Chen, P. Wen, and Z. J. ACS N. Xu, “3D Flexible, Conductive, and Recyclable Ti3C2Tx MXene-Melamine Foam for High-Areal-Capacity and Long-Lifetime Alkali-Metal Anode,” ACS Nano, vol. 14, no. 7, pp. 11, 2020, http://dx.doi.org/10.1021/acsnano.0c03042.

Iqbal, Aamir, Faisal Shahzad, Kanit Hantanasirisakul, Myung-Ki Kim, Jisung Kwon, Junpyo Hong, Hyerim Kim, Daesin Kim, Yury Gogotsi, and Chong Min Koo. "Anomalous absorption of electromagnetic waves by 2D transition metal carbonitride Ti3CNT x (MXene)." Science 369, no. 6502, 446-450, 2020, https://doi.org/10.1126/science.aba7977.

C. Caloz, and T. J. I. M. S. I. m. S. d. p. P. Itoh, “Novel microwave devices and structures based on the transmission line approach of meta-materials,” Science, 2003, http://dx.doi.org/10.1126/science.aba7977.

S. Geetha, K. K. S. Kumar, C. R. K. Rao, M. Vijayan, and D. C. J. J. o. A. P. S. Trivedi, “EMI shielding: Methods and materials—A review,” Journal of Applied Polymer Science, vol. 112, no. 4, pp. 2073-2086, 2010, http://dx.doi.org/10.1002/app.29812.

A. A. Isari, A. Ghaffarkhah, S. A. Hashemi, S. Wuttke, and M. J. A. M. Arjmand, “Structural design for EMI shielding: from underlying mechanisms to common pitfalls,” Advanced Materials, vol. 36, no. 24, pp. 2310683, 2024, http://dx.doi.org/10.1002/adma.202310683.

W. Lei, C. Jiawei, Z. Y. W. Y. Y. H. D. X. J. A. composites, and h. materials, “Current advances and future perspectives of MXene-based electromagnetic interference shielding materials,” vol. 6, no. 5, 2023

Y. Wang, Y. N. Gao, T. N. Yue, X. D. Chen, and M. J. A. S. S. Wang, “Achieving high-performance and tunable microwave shielding inmulti-walled carbon nanotubes/polydimethylsiloxane composites containing liquid metals,” Applied Surface Science, vol. 563, no. Octa15, pp. 150255.1-150255.11, 2021, http://dx.doi.org/10.1016/j.apsusc.2021.150255.

Y. Shi, S. Xu, J. Du, and J. J. M. T. P. Qiu, “Strain-responsive 3D hierarchical composites for smart microwave absorption modulation within broad C-Ku band,” Materials Today Physics, vol. 27, 2022, http://dx.doi.org/10.1016/j.mtphys.2022.100823.

T. Someya, Z. Bao, and G. G. J. N. Malliaras, “The rise of plastic bioelectronics,” Nature, vol. 540, no. 7633, pp. 379-385, 2016, http://dx.doi.org/10.1038/nature21004.

Y.-Y. Wang, Z.-H. Zhou, C.-G. Zhou, W.-J. Sun, J.-F. Gao, K. Dai, D.-X. Yan, Z.-M. J. A. a. m. Li, and interfaces, “Lightweight and robust carbon nanotube/polyimide foam for efficient and heat-resistant electromagnetic interference shielding and microwave absorption,” ACS Applied Materials & Interfaces, vol. 12, no. 7, pp. 8704-8712, 2020, http://dx.doi.org/10.1021/acsami.9b21048.

C. Weng, G. Wang, Z. Dai, Y. Pei, L. Liu, and Z. J. N. Zhang, “Buckled AgNW/MXene hybrid hierarchical sponges for high-performance electromagnetic interference shielding,” Nanoscale, vol. 11, no. 47, pp. 22804-22812, 2019, http://dx.doi.org/10.1039/c9nr07988b.

W. Yuan, H. Liu, X. Wang, L. Huang, F. Yin, Y. J. C. P. A. A. S. Yuan, and Manufacturing, “Conductive MXene/melamine sponge combined with 3D printing resin base prepared as an electromagnetic interferences shielding switch,” Composites Part A: Applied Science and Manufacturing, vol. 143, pp. 106238, 2021, http://dx.doi.org/10.1016/j.compositesa.2020.106238.

X. Jia, B. Shen, L. Zhang, and W. J. C. Zheng, “Construction of compressible Polymer/MXene composite foams for high-performance absorption-dominated electromagnetic shielding with ultra-low reflectivity,” Carbon, vol. 176, pp. 660-661, 2021, http://dx.doi.org/10.1016/j.carbon.2020.11.036.

Y. Yu, P. Yi, W. Xu, X. Sun, G. Deng, X. Liu, J. Shui, and R. J. N.-M. L. Yu, “Environmentally Tough and Stretchable MXene Organohydrogel with Exceptionally Enhanced Electromagnetic Interference Shielding Performances,” 2022, http://dx.doi.org/10.1007/s40820-022-00819-3.

H. Abbasi, M. Antunes, and J. I. J. P. i. M. S. Velasco, “Recent advances in carbon-based polymer nanocomposites for electromagnetic interference shielding,” Progress in Materials Science, vol. 103, pp. 319-373, 2019, http://dx.doi.org/10.1016/j.pmatsci.2019.02.003.

J. Ma, M. Zhan, K. J. A. A. M. Wang, and Interfaces, “Ultralightweight silver nanowires hybrid polyimide composite foams for high-performance electromagnetic interference shielding,” ACS Applied Materials & Interfaces, vol. 7, no. 1, pp. 563-76, 2015, http://dx.doi.org/10.1021/am5067095.

A. Sheng, W. Ren, Y. Yang, D.-X. Yan, H. Duan, G. Zhao, Y. Liu, Z.-M. J. C. P. A. A. S. Li, and Manufacturing, “Multilayer WPU conductive composites with controllable electro-magnetic gradient for absorption-dominated electromagnetic interference shielding,” Composites Part A: Applied Science and Manufacturing, vol. 129, pp. 105692, 2020, http://dx.doi.org/10.1016/j.compositesa.2019.105692.

H. Sun, Y. Zhao, S. Jiao, C. Wang, Y. Jia, K. Dai, G. Zheng, C. Liu, P. Wan, and C. J. A. F. M. Shen, “Environment tolerant conductive nanocomposite organohydrogels as flexible strain sensors and power sources for sustainable electronics,” Advanced Functional Materials, vol. 31, no. 24, pp. 2101696, 2021, http://dx.doi.org/10.1002/adfm.202101696.

Y. Niu, H. Liu, R. He, M. Luo, M. Shu, and F. J. S. Xu, “Environmentally Compatible Wearable Electronics Based on Ionically Conductive Organohydrogels for Health Monitoring with Thermal Compatibility, Anti‐Dehydration, and Underwater Adhesion,” Small, vol. 17, no. 24, pp. 2101151, 2021, http://dx.doi.org/10.1002/smll.202101151.

X. Jia, B. Shen, L. Zhang, and W. J. C. E. J. Zheng, “Construction of shape-memory carbon foam composites for adjustable EMI shielding under self-fixable mechanical deformation,” Chemical Engineering Journal, vol. 405, pp. 126927, 2021, http://dx.doi.org/10.1016/j.cej.2020.126927.

Zeng, Zhiyong, Jv Li, Leimei Fang, Chuanru Zheng, Hongmei Chen, Jian Huang, Kun Qian, Haoxuan Li, and Wenbing Li. "Flexible and durable shape memory EVA/MXene/EVA fiber membrane for programmable EMI shielding." Chemical Engineering Journal 501, 157599, 2024, http://dx.doi.org/10.1016/j.cej.2024.157599.

Y. J. He, Y. W. Shao, Y. Y. J. A. a. m. Xiao, and interfaces, “Multifunctional Phase Change Composites Based on Elastic MXene/Silver Nanowire Sponges for Excellent Thermal/Solar/Electric Energy Storage, Shape Memory, and Adjustable Electromagnetic Interference Shielding Functions,” ACS Applied Materials & Interfaces, no. 4, pp. 14, 2022, http://dx.doi.org/10.1021/acsami.1c23303.

A. V. Menon, G. Madras, and S. J. C. E. J. Bose, “Shape memory polyurethane nanocomposites with porous architectures for enhanced microwave shielding,” Chemical Engineering Journal, vol. 352, pp. 590-600, 2018, http://dx.doi.org/10.1016/j.cej.2018.07.048.

Y. Yan, H. Xia, Y. Qiu, Z. Xu, and Q. Q. J. R. A. Ni, “Fabrication of gradient vapor grown carbon fiber based polyurethane foam for shape memory driven microwave shielding,” RSC Advances, vol. 9, 2019, http://dx.doi.org/10.1039/C9RA00028C.

H. Lu, Z. Li, X. Qi, L. Xu, Z. Chi, D. Duan, M. Z. Islam, W. Wang, X. Jin, Y. J. C. S. Zhu, and Technology, “Flexible, electrothermal-driven controllable carbon fiber/poly (ethylene-co-vinyl acetate) shape memory composites for electromagnetic shielding,” Composites Science and Technology, vol. 207, pp. 108697, 2021, http://dx.doi.org/10.1016/j.compscitech.2021.108697.

M. Fang, L. Huang, Z. Cui, P. Yi, H. Zou, X. Li, G. Deng, C. Chen, Z. Geng, and J. J. A. F. M. He, “Phase‐Transition Microcapacitor Network in Organohydrogel for Absorption‐Dominated Electromagnetic Interference Shielding and Multi‐Mode Intelligent Responsiveness,” vol. 35, no. 18, 2025.

H. Qian, W. Jiang, X. Shi, Q. Cao, B. Jiang, and Y. J. C. Huang, “Pushing electromagnetic interference shielding self-enhanced based on smart Ti3C2Tx-WVO2 thermal management composite,” Carbon, vol. 210, no. 000, pp. 8, 2023, http://dx.doi.org/10.1016/j.carbon.2023.118081.

W. Chen, C. Li, D. Wang, S. Gao, C. Zhang, H. Guo, W. An, S. Guo, and G. J. P. C. C. P. Wu, “A dual ultra-broadband switchable high-performance terahertz absorber based on hybrid graphene and vanadium dioxide,” Physical Chemistry Chemical Physics, vol. 25, no. 30, pp. 20414-20421, 2023, http://dx.doi.org/10.1039/D3CP01312J.

D. Y. Li, L. X. Liu, Q. W. J. A. a. m. Wang, and interfaces, “Functional Polyaniline/MXene/Cotton Fabrics with Acid/Alkali-Responsive and Tunable Electromagnetic Interference Shielding Performances,” ACS Applied Materials & Interfaces, no. 10, pp. 14, 2022, http://dx.doi.org/10.1021/acsami.2c00797.

B. Zhao, P. Bai, M. Yuan, Z. Yan, B. Fan, R. Zhang, and R. J. C. Che, “Recyclable magnetic carbon foams possessing voltage-controllable electromagnetic shielding and oil/water separation,” Carbon, vol. 197, pp. 570-578, 2022, http://dx.doi.org/10.1016/j.carbon.2022.06.010.

Wei, Jingjiang, Yunfei Yang, Fei Pan, Kun Yang, Yanqing Wang, Zhihui Zeng, Qingyuan Wang, and Zhengyi Fu. "Hofmeister effect-inspired Ti3C2Tx MXene-based robust, multifunctional hydrogels." Composites Part A: Applied Science and Manufacturing 172, 107626, 2023, http://dx.doi.org/10.1016/j.compositesa.2023.107626.

L. Mei, W. Ouyang, L. Xu, Y. Huang, Q. Liu, Y. Bai, Q. Lu, T. Luo, and Z. J. S. Wu, “Super Tough Multifunctional MXene/PAA‐CS Double Network Hydrogels with High Mechanical Sensing Properties and Excellent EMI Shielding Performance,” Small, vol. 21, no. 6, pp. 2410687, 2025, http://dx.doi.org/10.1002/smll.202410687.

H. Meikang, Z. Danzhen, and S. C. E. M. B. T. R. J. K. Y. J. N. nanotechnology, “Electrochemically modulated interaction of MXenes with microwaves,” Nature Nanotechnology, vol. 18, no. 4, pp. 373-379, 2023, http://dx.doi.org/10.1038/s41565-022-01308-9.

Jiang, PZ., Deng, Z., Min, P. et al. Direct ink writing of multifunctional gratings with gel-like MXene/norepinephrine ink for dynamic electromagnetic interference shielding and patterned Joule heating. Nano Res. 17, 1585–1594, 2024, https://doi.org/10.1007/s12274-023-6044-9.

Wei, Yuyi, Chuanshuang Hu, Zhenhua Dai, Yanfei Zhang, Weiwei Zhang, and Xiuyi Lin. "Highly anisotropic MXene@ Wood composites for tunable electromagnetic interference shielding." Composites Part A: Applied Science and Manufacturing 168, 107476, 2023, https://doi.org/10.1016/j.compositesa.2023.107476.